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TiO2 as additive

https://doi.org/10.3390/su14084750

“The utilization of TiO2 nanoparticles for the process of solvent regeneration in CO2 capture process is limited and should be improved. However, it was demonstrated that the TiO2 nanoparticle contributed to an impressive CO2 absorption enhancement [100,116]. With the increase in the particle loading, the viscosity of the TiO2 employed solvent demonstrated a significant increase. This can be explained by the high density of the TiO2 nanoparticle at 5500–6000 kg/m3, which, in fact, is the highest among all the other particles in review. This is an undesirable property as an increase in viscosity causes a reduction in the diffusion coefficient and would restrain the growth of bubbles, resulting in the reduction of the gas-liquid mass transfer rate.

TiO2 was also reported to have catalytic effects on enhancing the desorption performance of CO2 capture [27]. The TiO2 possesses Lewis acid (electron acceptor) sites on the surface of the catalyst, which is why it experiences an improved CO2 stripping rate. This is, however, not as significant as the other catalysts studied by the author and team. In terms of its other properties, the TiO2 is still prone to agglomeration and is thermally stable, proving its suitability to be employed for a typical regeneration temperature. According to a study [117], the TiO2 nanoparticle powder showed two main stages of mass loss. The first being 6–8%, between 25 and 100 °C, which was due to water loss on the surface of the TiO2. The second one was attributed to the loss of the organic matter after the rupture of the polymer chain due to the high temperature of 250 and 480 °C. This corresponded to an additional weight loss of 35%. In addition to that, it was also a recyclable nanoparticle with slight toxicity and was relatively harmless to the environment.”

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