https://doi.org/10.3390/molecules27175608 “In addition to the potential for large-scale synthesis of ZIF-94 at room temperature, we also needed to evaluate it in terms of structural stability
https://doi.org/10.3390/molecules27175608 “The previous experiments demonstrated that ZIF-94 has high CO2 adsorption capacity and satisfactory CO2/N2 selectivity; the phenomena prompted us to investigate the feasibility of using ZIF-94
https://doi.org/10.1016/j.mtsust.2022.100149 “Light-induced local heating is also another reason for the reduction of CO2 uptake. Bleger et al. [42] reported that the absorbed solar energy of F-azo-MIL-53 (Al)
https://doi.org/10.1016/j.mtsust.2022.100149 “Ladewig’s group observed that CO2 had a lower affinity toward Azo-UiO-66 in UV irradiation conditions, which caused the instantaneous release of CO2 once it was exposed
https://doi.org/10.1016/j.mtsust.2022.100149 “However, in later works, Poloni’s group demonstrated that the blocking of the adsorbing sites at the metal nodes by the phenyl ring in cis isomer was
https://doi.org/10.1016/j.mtsust.2022.100149 “Aida et al. [12] reported that it is the modulation of the polar interaction between CO2 molecules and the channel wall rather than the steric effect that caused
https://doi.org/10.1016/j.mtsust.2022.100149 “Hill et al. [31] firstly proposed that the increase of light-induced MOF surface energy triggered the CO2 release. Under the UV light irradiation, the intermolecular interactions
“In terms of maximising low temperature adsorption, porous solid sorbents, such as zeolites, activated carbons, and metal–organic frameworks (MOFs), have certain advantages.29 Unlike chemisorbents, they form
https://doi.org/10.1039/D1MA00919B “Based on CO2 isotherms at different temperatures, the CO2 adsorption enthalpy (Qst) was calculated by using the Clausius–Clapeyron relation (see the calculated procedure in the ESI,†
https://doi.org/10.1016/j.micromeso.2021.111548 “The diffusion of CO2 in UU-200 and the selected Bi-MOFs were studied using a gravimetric method at 303 K (Fig. 8 and Fig. S20). The adsorption of CO2 was
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