https://doi.org/10.1002/cplu.202000072 ” Although the use of MOFs for DAC remains a very promising methodology to reduce the impact of atmospheric CO2 on the global climate, its
https://doi.org/10.1002/cplu.202000072 “The current literature shows that despite the huge efforts to design and synthetize a material with high CO2 capacity that can be easily regenerated, only
https://doi.org/10.1002/cplu.202000072 ” Usually, the peculiarities of MOFs cannot be exploited to their full potential, due to certain limitations in stability, shaping and scalability. Considering these
https://doi.org/10.1002/cplu.202000072 ” MOFs pores offer a distinctive setting for confinement processes. Small molecules can be hosted within the MOF cavities, generating a significant alteration of
https://doi.org/10.1002/cplu.202000072 ” The introduction of designated uncoordinated functional groups (−NH2, (−COOH or (−OH) in the organic linkers is a typical method to build a MOF
https://doi.org/10.1002/cplu.202000072 ” The heat of adsorption (Qst) of a guest molecule is the fundamental physical characteristic, which drives the physisorption of CO2 to a MOF compound.
https://doi.org/10.1016/j.ijggc.2020.103005 ” MOFs are a new class of versatile crystalline materials comprising organic ligand – attached metallic ions or clusters arranged in an open network
https://doi.org/10.1016/j.mtsust.2022.100149 “Until now, most efforts have been devoted to the development of azobenzene based photoswitchable MOFs; it is expected that more other photochromic units, such
https://doi.org/10.1016/j.mtsust.2022.100149 “Spiropyran (SP) is also another group of photochromic materials with two orthogonal π-networks bonded by a central tetrahedral carbon (Cspiro). When exposing to UV irradiation, a
https://doi.org/10.1016/j.mtsust.2022.100149 ” Although the azobenzene class of photochromes is known to experience drastic structural alteration, only modest light absorption changes are exhibited and the photo-induced
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